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Their Jolie-Pitt Foundation raised over $13million last year.
Of that figure, over half was handed out to various charities, according to a tax return obtained by the Hollywood Reporter.
Among the recipients were Global Health ($2million), Human Rights Watch ($1million) and Brad's Make it Right Foundation ($1million).
The donations made by Angelina, 33, and Brad, 45, last year were more than double the amount they allocated to charitable organisations in 2007.